Electrified CO2 valorization driven by direct Joule heating of catalytic cellular substrates
نویسندگان
چکیده
The growing environmental concerns have driven catalytic CO2 valorization as a forward-looking solution to mitigate the carbon footprint of valuable chemical products. conversion processes into synthesis gas, such reforming methane (CRM) or reverse water–gas shift (RWGS), may strategic role for future sustainable production chemicals and energy carriers. However, fuel combustion supply heat associated endothermic reactions would result in unwanted emissions, frustrating overall objective. Electrification represent technological an issue. Here we report promising approach direct electrification (eCRM) (eRWGS) washcoated structured reactors. We employ catalytically activated open-cell foams that provide optimal mass transfer properties serve Joule heating substrates via reaction with hydrogen. proposed reactor system Joule-heated Rh/Al2O3-coated foam exhibited excellent electrical stability more than 75 h, operating up 800 °C approaching equilibrium at high space velocity, i.e., GHSV 600 100 kNl/kgcat/h eRWGS eCRM, respectively. Such concept has potential ensure remarkably low specific demand valorization. Assuming optimized process configuration approx. 0.7 kWh/Nm3CO2 is calculated eRWGS. By replacing by renewable electricity, electrified important dealing intermittent nature sources storing footprint.
منابع مشابه
Remote Joule heating by a carbon nanotube.
Minimizing Joule heating remains an important goal in the design of electronic devices. The prevailing model of Joule heating relies on a simple semiclassical picture in which electrons collide with the atoms of a conductor, generating heat locally and only in regions of non-zero current density, and this model has been supported by most experiments. Recently, however, it has been predicted tha...
متن کاملMagnetic properties and giant magnetoresistance of magnetic granular Co10Cu90 alloys obtained by direct‐current joule heating
متن کامل
Jupiter Thermospheric General Circulation Model (JTGCM): Global structure and dynamics driven by auroral and Joule heating
[1] A growing multispectral database plus recent Galileo descent measurements are being used to construct a self-consistent picture of the Jupiter thermosphere/ionosphere system. The proper characterization of Jupiter’s upper atmosphere, embedded ionosphere, and auroral features requires the examination of underlying processes, including the feedbacks of energetics, neutral-ion dynamics, compos...
متن کاملPolycrystalline Silicon Produced by Joule-Heating Induced Crystallization
An electric field was applied to a conductive layer to induce Joule heating in order to generate the intense heat needed to carry out the crystallization of amorphous silicon. Complete crystallization was observed via Joule heating under typical processing conditions. Crystallization was accomplished throughout the sample within the range of microseconds of the heating, thus demonstrating the p...
متن کاملNanomechanical Optical Fiber with Embedded Electrodes Actuated by Joule Heating
Nanomechanical optical fibers with metal electrodes embedded in the jacket were fabricated by a multi-material co-draw technique. At the center of the fibers, two glass cores suspended by thin membranes and surrounded by air form a directional coupler that is highly temperature-dependent. We demonstrate optical switching between the two fiber cores by Joule heating of the electrodes with as lit...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Chemical Engineering Journal
سال: 2023
ISSN: ['1873-3212', '1385-8947']
DOI: https://doi.org/10.1016/j.cej.2023.143154